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Issue 47, 2016
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Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

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Abstract

Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M63-O)43-OH)4(OH)4(H2O)4(TCPB)2] crystallise in the scu topology, a connectivity hitherto unreported for Zr-MOFs with tetracarboxylate linker molecules. Zr-CAU-24 exhibits UV/blue ligand-based luminescence.

Graphical abstract: Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

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Article information


Submitted
05 Oct 2016
Accepted
08 Nov 2016
First published
08 Nov 2016

This article is Open Access

Dalton Trans., 2016,45, 18822-18826
Article type
Communication

Synthesis and structure of Zr(IV)- and Ce(IV)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

M. Lammert, H. Reinsch, C. A. Murray, M. T. Wharmby, H. Terraschke and N. Stock, Dalton Trans., 2016, 45, 18822 DOI: 10.1039/C6DT03852B

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