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Issue 35, 2016
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First cage-like pentanuclear Co(ii)-silsesquioxane

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A new pentanuclear “cylinder”-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

Graphical abstract: First cage-like pentanuclear Co(ii)-silsesquioxane

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Article information

20 May 2016
08 Jul 2016
First published
08 Jul 2016

Dalton Trans., 2016,45, 13663-13666
Article type

First cage-like pentanuclear Co(II)-silsesquioxane

A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. A. Korlyukov, M. A. Es'kova, J. Long, J. Larionova, Y. Guari, L. S. Shul'pina, N. S. Ikonnikov, A. L. Trigub, Y. V. Zubavichus, I. E. Golub, E. S. Shubina and G. B. Shul'pin, Dalton Trans., 2016, 45, 13663
DOI: 10.1039/C6DT02026G

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