Issue 35, 2016

First cage-like pentanuclear Co(ii)-silsesquioxane

Abstract

A new pentanuclear “cylinder”-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

Graphical abstract: First cage-like pentanuclear Co(ii)-silsesquioxane

Supplementary files

Article information

Article type
Communication
Submitted
20 May 2016
Accepted
08 Jul 2016
First published
08 Jul 2016

Dalton Trans., 2016,45, 13663-13666

First cage-like pentanuclear Co(II)-silsesquioxane

A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. A. Korlyukov, M. A. Es'kova, J. Long, J. Larionova, Y. Guari, L. S. Shul'pina, N. S. Ikonnikov, A. L. Trigub, Y. V. Zubavichus, I. E. Golub, E. S. Shubina and G. B. Shul'pin, Dalton Trans., 2016, 45, 13663 DOI: 10.1039/C6DT02026G

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