Issue 29, 2016
From the journal:

Dalton Transactions

Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex†

Cristina Alvariño,a   Carlos Platas-Iglesias,a   Víctor Blanco,b   Marcos D. García,*a   Carlos Peinador*a  and  José M. Quintelaa  

* Corresponding authors

a Departamento de Química Fundamental and Centro de Investigacións Científicas Avanzadas (CICA), Facultad de Ciencias, Universidade da Coruña, E-15071 A Coruña, Spain
E-mail: carlos.peinador@udc.es, marcos.garcia1@udc.es

b Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada, Campus Fuentenueva S/N, 18071 Granada, Spain

Abstract

Concentration, temperature and/or solvent polarity control the speciation on the metal-directed self-assembly of a ditopic pyridyl ligand L with cis-protected Pd(II) metal centers. This results into a controllable dynamic system, involving a [Pd2L2]6+ metallacycle and a [Pd4L4]12+ ring-in-ring complex.

Graphical abstract: Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex

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Article information

DOI
https://doi.org/10.1039/C6DT01835A
Article type
Communication
Submitted
10 May 2016
Accepted
03 Jun 2016
First published
06 Jun 2016
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 11611-11615

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Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex

C. Alvariño, C. Platas-Iglesias, V. Blanco, M. D. García, C. Peinador and J. M. Quintela, Dalton Trans., 2016, 45, 11611 DOI: 10.1039/C6DT01835A

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