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Issue 18, 2016
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Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

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Abstract

We report the iridium hydride-mediated Si–Cl and Ge–Cl σ-bond activation in a low-polarity toluene solution owing to diphosphine-chelation, in which the Si–Cl and Ge–Cl σ-bonds are readily cleaved through an SN2-type pathway via the formation of a free chloride anion.

Graphical abstract: Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

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Publication details

The article was received on 01 Jan 2016, accepted on 18 Feb 2016 and first published on 19 Feb 2016


Article type: Paper
DOI: 10.1039/C6DT00003G
Dalton Trans., 2016,45, 7570-7580

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    Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

    H. Kameo, K. Ikeda, S. Sakaki, S. Takemoto, H. Nakazawa and H. Matsuzaka, Dalton Trans., 2016, 45, 7570
    DOI: 10.1039/C6DT00003G

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