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Issue 2, 2016
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New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands

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Abstract

(μ-1,2-Peroxo)diiron(III) complexes (2-R) with dinucleating ligands (R-L) generated from the reaction of bis(μ-hydroxo)diiron(II) complexes [Fe2(R-L)(OH)2]2+ (1-R) with dioxygen in acetone at −20 °C provide a diiron-centred electrophilic oxidant, presumably diiron(IV)-oxo species, which is involved in aromatic ligand hydroxylation.

Graphical abstract: New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands

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The article was received on 19 Oct 2015, accepted on 23 Nov 2015 and first published on 23 Nov 2015


Article type: Communication
DOI: 10.1039/C5DT04088D
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Dalton Trans., 2016,45, 469-473

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    New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands

    M. Sekino, H. Furutachi, K. Tasaki, T. Ishikawa, S. Mori, S. Fujinami, S. Akine, Y. Sakata, T. Nomura, T. Ogura, T. Kitagawa and M. Suzuki, Dalton Trans., 2016, 45, 469
    DOI: 10.1039/C5DT04088D

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