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Issue 4, 2016
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Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments

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Abstract

Iron complexes, [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl: 1, Br: 2, I: 3) containing two terminal indium fragments, were synthesized. Their structures were determined using X-ray analysis. The bonding mode of the Fe–In bonds in the anionic part was investigated using 57Fe Mössbauer and IR spectroscopy. These complexes represent the first example of transition metal complexes containing two terminal indium fragments.

Graphical abstract: Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments

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Publication details

The article was received on 25 Sep 2015, accepted on 11 Dec 2015 and first published on 24 Dec 2015


Article type: Communication
DOI: 10.1039/C5DT03745J
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Dalton Trans., 2016,45, 1327-1330

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    Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments

    M. Itazaki, M. Ito, S. Nakashima and H. Nakazawa, Dalton Trans., 2016, 45, 1327
    DOI: 10.1039/C5DT03745J

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