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Issue 5, 2016
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Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

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Abstract

We report the synthesis by RAFT polymerization of well-defined diblock copolymers bearing carbamoylmethylphosphonate moieties which proved to sorb gadolinium. These poly(diethyl-6-(acrylamido)hexylcarbamoylmethylphosphonate-b-acrylic acid) (P(CPAAm6C-b-AA)) copolymers were able to self-assemble as a function of temperature, above their cloud point value.

Graphical abstract: Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

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Publication details

The article was received on 25 Aug 2015, accepted on 18 Sep 2015 and first published on 18 Sep 2015


Article type: Communication
DOI: 10.1039/C5DT03289J
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Dalton Trans., 2016,45, 1881-1885

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    Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

    F. Azemar, D. Gomes-Rodrigues, J. Robin and S. Monge, Dalton Trans., 2016, 45, 1881
    DOI: 10.1039/C5DT03289J

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