Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 5, 2016
Previous Article Next Article

Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks

Author affiliations

Abstract

Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the formation of the bicyclic tetraphosphane Mes*P4Mes* (5) and its unknown Lewis acid adduct 5·GaCl3. In this context, the endoexo isomer of 5 was fully characterized for the first time. The synthesis was achieved by reactions involving “self-assembly” of the P4 scaffold from P1 building blocks (i.e. primary phosphanes) or by reactions starting from P2 or P4 scaffolds (i.e. a diphosphene or cyclic tetraphosphane). Furthermore, interconversion between the exoexo and endoexo isomer were studied by 31P NMR spectroscopy. All compounds were fully characterized by experimental as well as computational methods.

Graphical abstract: Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks

Back to tab navigation

Supplementary files

Article information


Submitted
20 Jul 2015
Accepted
28 Aug 2015
First published
28 Aug 2015

This article is Open Access

Dalton Trans., 2016,45, 1998-2007
Article type
Paper
Author version available

Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks

J. Bresien, K. Faust, C. Hering-Junghans, J. Rothe, A. Schulz and A. Villinger, Dalton Trans., 2016, 45, 1998
DOI: 10.1039/C5DT02757H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements