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Issue 5, 2016
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Synthesis and characterization of manganese triple-decker complexes

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Abstract

The use of the highly sterically demanding CpBIG ligand (CpBIG = C5(4-nBuC6H4)5) and white phosphorus (P4) enables the synthesis of new P-rich derivatives of the rare Pn ligand complexes of manganese. The obtained complexes, [{CpBIGMn}2(μ,η5:5-P5)] (2) and [{CpBIGMn}2(μ,η2:2-P2)2] (3), exhibit the highest number of P atoms in this class of manganese compounds identified by X-ray structure analyses. The EPR spectrum of the 29 VE triple-decker complex 2 shows one unpaired electron coupling with two 5/2 spin Mn nuclei.

Graphical abstract: Synthesis and characterization of manganese triple-decker complexes

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Article information


Submitted
08 May 2015
Accepted
02 Jun 2015
First published
04 Jun 2015

Dalton Trans., 2016,45, 1962-1966
Article type
Paper
Author version available

Synthesis and characterization of manganese triple-decker complexes

S. Heinl, G. Balázs, M. Bodensteiner and M. Scheer, Dalton Trans., 2016, 45, 1962
DOI: 10.1039/C5DT01750E

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