Jump to main content
Jump to site search

Issue 4, 2016
Previous Article Next Article

Single-molecule insight into Wurtz reactions on metal surfaces

Author affiliations


Wurtz reactions feature the dehalogenated coupling of alkyl halides. In comparison to their widely investigated counterparts, Ullmann reactions, Wurtz reactions have however been scarcely explored on surfaces. Herein, by combining high-resolution STM imaging and DFT calculations, we have systematically investigated Wurtz reactions on three chemically different metal surfaces including Cu(110), Ag(110) and Au(111). We find that the Wurtz reactions could be achieved on all three surfaces, and the temperatures for triggering the reactions are in the order of Cu(110) > Ag(110) > Au(111). Moreover, DFT calculations have been performed to unravel the pathways of on-surface Wurtz reactions and identify three basic steps of the reactions including debromination, diffusion and coupling processes. Interestingly, we found that the mechanism of the on-surface Wurtz reaction is intrinsically different from the Ullmann reaction and it is revealed that the coupling process is the rate-limiting step of Wurtz reactions on three different substrates. These findings have given a comprehensive picture of Wurtz reactions on metal surfaces and demonstrated that such a reaction could be an alternative reaction scheme for advanced on-surface synthesis.

Graphical abstract: Single-molecule insight into Wurtz reactions on metal surfaces

Back to tab navigation

Supplementary files

Publication details

The article was received on 23 Oct 2015, accepted on 11 Dec 2015 and first published on 14 Dec 2015

Article type: Paper
DOI: 10.1039/C5CP06459G
Phys. Chem. Chem. Phys., 2016,18, 2730-2735

  •   Request permissions

    Single-molecule insight into Wurtz reactions on metal surfaces

    Q. Sun, L. Cai, Y. Ding, H. Ma, C. Yuan and W. Xu, Phys. Chem. Chem. Phys., 2016, 18, 2730
    DOI: 10.1039/C5CP06459G

Search articles by author