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Issue 24, 2016
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Order–disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH4]2[NiCd(SCN)6]

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Abstract

The first thiocyanate-bridged double perovskite-type coordination polymer [NH4]2[NiCd(SCN)6] is reported here, which undergoes a reversible structural phase transition at around 120 K. An order–disorder mechanism for this transition is disclosed by X-ray structural analyses, dielectric measurement, as well as molecular dynamics simulations.

Graphical abstract: Order–disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH4]2[NiCd(SCN)6]

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Publication details

The article was received on 19 Apr 2016, accepted on 09 May 2016 and first published on 09 May 2016


Article type: Communication
DOI: 10.1039/C6CE00898D
CrystEngComm, 2016,18, 4495-4498

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    Order–disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH4]2[NiCd(SCN)6]

    K. Xie, W. Xu, C. He, B. Huang, Z. Du, Y. Su, W. Zhang and X. Chen, CrystEngComm, 2016, 18, 4495
    DOI: 10.1039/C6CE00898D

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