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Issue 97, 2016
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Palladium catalyzed selective distal C–H olefination of biaryl systems

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Abstract

Palladium catalyzed selective distal C–H activation with nitrile based templates has been of significant research interest in recent times. In this report, we disclose the distal C–H olefination of biphenyl systems with high regio- and stereo-selectivity and useful synthetic yields. The utility of this method has been demonstrated through its wide olefin scope, its operation at the gram scale and the easy removal/recovery of the directing group.

Graphical abstract: Palladium catalyzed selective distal C–H olefination of biaryl systems

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Publication details

The article was received on 27 Sep 2016, accepted on 09 Nov 2016 and first published on 09 Nov 2016


Article type: Communication
DOI: 10.1039/C6CC07861C
Chem. Commun., 2016,52, 14003-14006

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    Palladium catalyzed selective distal C–H olefination of biaryl systems

    S. Maity, E. Hoque, U. Dhawa and D. Maiti, Chem. Commun., 2016, 52, 14003
    DOI: 10.1039/C6CC07861C

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