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Issue 93, 2016
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A MOF-membrane based on the covalent bonding driven assembly of a NMOF with an organic oligomer and its application in membrane reactors

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Abstract

A UiO-66-MOF-based membrane UiO-66-TEM (1) was prepared by the assembly of methacrylamide-decorated UiO-66-NH-Met with a thiol side chain-attached polysiloxane (PSI-SH) via a photoinduced thiol–ene click reaction. The obtained membrane 1 can be a platform to support Au nanoparticles (Au NPs) to generate an Au–MOF–polymer composite membrane Au@UiO-66-TEM (2). 1 and 2 can be used to build highly efficient continuous flow-through membrane reactors for Knoevenagel condensation of 4-nitrobenzaldehyde with malononitrile and 4-nitrophenol (4-NP) reduction at ambient temperature, respectively.

Graphical abstract: A MOF-membrane based on the covalent bonding driven assembly of a NMOF with an organic oligomer and its application in membrane reactors

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Article information


Submitted
04 Aug 2016
Accepted
26 Sep 2016
First published
26 Sep 2016

Chem. Commun., 2016,52, 13564-13567
Article type
Communication

A MOF-membrane based on the covalent bonding driven assembly of a NMOF with an organic oligomer and its application in membrane reactors

W. Jiang, L. Ding, B. Yao, J. Wang, G. Chen, Y. Li, J. Ma, J. Ji, Y. Dong and Y. Dong, Chem. Commun., 2016, 52, 13564
DOI: 10.1039/C6CC06427B

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