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Issue 86, 2016
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Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit

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Abstract

A new, microporous Zr-MOF was obtained using 2,5-pyrazinedicarboxylic acid (H2PzDC). The linker leads to the formation of a new 1D inorganic building unit composed of μ-OH bridged {Zr6O4(OH4)} clusters which are arranged in a hexagonal array and connected by the PzDC2− ions. The structure was determined from powder X-ray diffraction data.

Graphical abstract: Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit

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Supplementary files

Article information


Submitted
29 Jul 2016
Accepted
01 Sep 2016
First published
01 Sep 2016

This article is Open Access

Chem. Commun., 2016,52, 12698-12701
Article type
Communication

Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit

S. Waitschat, H. Reinsch and N. Stock, Chem. Commun., 2016, 52, 12698
DOI: 10.1039/C6CC06287C

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