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Issue 59, 2016
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A three-coordinate Fe(ii) center within a [3Fe–(μ3-S)] cluster that provides an accessible coordination site

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Abstract

A μ3-sulfide bridged triiron cluster(II,II,III) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.

Graphical abstract: A three-coordinate Fe(ii) center within a [3Fe–(μ3-S)] cluster that provides an accessible coordination site

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Article information


Submitted
03 Jun 2016
Accepted
27 Jun 2016
First published
01 Jul 2016

Chem. Commun., 2016,52, 9295-9298
Article type
Communication

A three-coordinate Fe(II) center within a [3Fe–(μ3-S)] cluster that provides an accessible coordination site

Y. Lee, K. A. Abboud, R. García-Serres and L. J. Murray, Chem. Commun., 2016, 52, 9295
DOI: 10.1039/C6CC04671A

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