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Issue 59, 2016
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Silver migration between Au38(SC2H4Ph)24 and doped AgxAu38−x(SC2H4Ph)24 nanoclusters

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Abstract

A fast redistribution of metal atoms occurs upon mixing the AgxAu38−x and Au38 nanoclusters in solution, as observed by mass spectrometry. Physical separation of AgxAu38−x and Au38 species by a dialysis membrane prohibits the metal migration, which suggests that collisions between the reacting clusters are at the origin of the observation.

Graphical abstract: Silver migration between Au38(SC2H4Ph)24 and doped AgxAu38−x(SC2H4Ph)24 nanoclusters

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Supplementary files

Article information


Submitted
27 May 2016
Accepted
17 Jun 2016
First published
17 Jun 2016

This article is Open Access

Chem. Commun., 2016,52, 9205-9207
Article type
Communication

Silver migration between Au38(SC2H4Ph)24 and doped AgxAu38−x(SC2H4Ph)24 nanoclusters

B. Zhang, G. Salassa and T. Bürgi, Chem. Commun., 2016, 52, 9205
DOI: 10.1039/C6CC04469G

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