Jump to main content
Jump to site search

Issue 54, 2016
Previous Article Next Article

Co(ii)-induced giant vibrational CD provides a new design of methods for rapid and sensitive chirality recognition

Author affiliations

Abstract

We designed a stereodynamic system, where the chirality of the analyte serves as a template for the helicity of the first coordination sphere of Co(II). Giant VCD bands induced by Co(II) allow the measurement of a completely significant and conclusive VCD spectrum in only a few seconds and/or on minute quantities of the analyte. This paves the way for the development of similar protocols, overcoming the limitations due to weak VCD signals for the assignment of absolute configurations.

Graphical abstract: Co(ii)-induced giant vibrational CD provides a new design of methods for rapid and sensitive chirality recognition

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 May 2016, accepted on 03 Jun 2016 and first published on 03 Jun 2016


Article type: Communication
DOI: 10.1039/C6CC04167A
Author version
available:
Download author version (PDF)
Chem. Commun., 2016,52, 8428-8431

  •   Request permissions

    Co(II)-induced giant vibrational CD provides a new design of methods for rapid and sensitive chirality recognition

    R. Berardozzi, E. Badetti, N. A. Carmo dos Santos, K. Wurst, G. Licini, G. Pescitelli, C. Zonta and L. Di Bari, Chem. Commun., 2016, 52, 8428
    DOI: 10.1039/C6CC04167A

Search articles by author

Spotlight

Advertisements