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Issue 64, 2016
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Advanced hybrid battery with a magnesium metal anode and a spinel LiMn2O4 cathode

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Abstract

Two Mg–Li dual salt hybrid electrolytes are developed, which exhibit excellent oxidative stability up to around 3.8 V (vs. Mg/Mg2+) on an aluminum current collector, enabling the successful coupling of several state-of-the-art lithium-ion intercalation cathodes (LiMn2O4, LiCoO2 and LiNi1/3Mn1/3Co1/3O2) with magnesium metal anodes. The Mg-LiMn2O4 battery delivers an initial discharge capacity of about 106 mA h g−1 with a working voltage of around 2.8 V (vs. Mg/Mg2+), highlighting the highest working voltage of rechargeable batteries with magnesium metal anodes to date.

Graphical abstract: Advanced hybrid battery with a magnesium metal anode and a spinel LiMn2O4 cathode

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Supplementary files

Article information


Submitted
16 May 2016
Accepted
11 Jul 2016
First published
11 Jul 2016

Chem. Commun., 2016,52, 9961-9964
Article type
Communication

Advanced hybrid battery with a magnesium metal anode and a spinel LiMn2O4 cathode

B. Pan, Z. Feng, N. Sa, S. Han, Q. Ma, P. Fenter, J. T. Vaughey, Z. Zhang and C. Liao, Chem. Commun., 2016, 52, 9961
DOI: 10.1039/C6CC04133G

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