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Issue 53, 2016
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The air-stable carbocation salt [(MeOC6H4)CPh2][BF4] in Lewis acid catalyzed hydrothiolation of alkenes

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Abstract

Markovnikov hydrothiolation of 1,1-disubstituted and trisubstituted olefins (20 examples) is catalyzed by Lewis acids, including the air-stable trityl-cation salt [(MeOC6H4)CPh2][BF4] 3.

Graphical abstract: The air-stable carbocation salt [(MeOC6H4)CPh2][BF4] in Lewis acid catalyzed hydrothiolation of alkenes

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Article information


Submitted
11 May 2016
Accepted
06 Jun 2016
First published
06 Jun 2016

Chem. Commun., 2016,52, 8291-8293
Article type
Communication

The air-stable carbocation salt [(MeOC6H4)CPh2][BF4] in Lewis acid catalyzed hydrothiolation of alkenes

E. Mosaferi, D. Ripsman and D. W. Stephan, Chem. Commun., 2016, 52, 8291
DOI: 10.1039/C6CC03970G

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