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Issue 44, 2016
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An unprecedented zero field neodymium(iii) single-ion magnet based on a phosphonic diamide

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Abstract

The axial ligation by the –P[double bond, length as m-dash]O group of a phosphonic diamide in an air-stable Nd(III) complex ensures a pseudo-D5h symmetry leading to the stabilization of the mJ = |±9/2〉 state; this in turn is responsible for the observed SIM behaviour at zero field and the slow relaxation of magnetization up to 8.0 K.

Graphical abstract: An unprecedented zero field neodymium(iii) single-ion magnet based on a phosphonic diamide

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Article information


Submitted
12 Apr 2016
Accepted
05 May 2016
First published
05 May 2016

Chem. Commun., 2016,52, 7168-7171
Article type
Communication

An unprecedented zero field neodymium(III) single-ion magnet based on a phosphonic diamide

S. K. Gupta, T. Rajeshkumar, G. Rajaraman and R. Murugavel, Chem. Commun., 2016, 52, 7168
DOI: 10.1039/C6CC03066A

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