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Issue 53, 2016
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Adsorption of two gas molecules at a single metal site in a metal–organic framework

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Abstract

One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules—specifically hydrogen, methane, or carbon dioxide.

Graphical abstract: Adsorption of two gas molecules at a single metal site in a metal–organic framework

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Article information


Submitted
23 Mar 2016
Accepted
03 Jun 2016
First published
06 Jun 2016

Chem. Commun., 2016,52, 8251-8254
Article type
Communication

Adsorption of two gas molecules at a single metal site in a metal–organic framework

T. Runčevski, M. T. Kapelewski, R. M. Torres-Gavosto, J. D. Tarver, C. M. Brown and J. R. Long, Chem. Commun., 2016, 52, 8251
DOI: 10.1039/C6CC02494G

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