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Issue 53, 2016
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Adsorption of two gas molecules at a single metal site in a metal–organic framework

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Abstract

One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules—specifically hydrogen, methane, or carbon dioxide.

Graphical abstract: Adsorption of two gas molecules at a single metal site in a metal–organic framework

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Publication details

The article was received on 23 Mar 2016, accepted on 03 Jun 2016 and first published on 06 Jun 2016


Article type: Communication
DOI: 10.1039/C6CC02494G
Chem. Commun., 2016,52, 8251-8254

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    Adsorption of two gas molecules at a single metal site in a metal–organic framework

    T. Runčevski, M. T. Kapelewski, R. M. Torres-Gavosto, J. D. Tarver, C. M. Brown and J. R. Long, Chem. Commun., 2016, 52, 8251
    DOI: 10.1039/C6CC02494G

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