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Issue 52, 2016
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Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

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Abstract

A manganese-catalyzed regioselective sp3 C–S bond formation through C–C bond cleavage of cyclobutanols is described. A variety of primary and secondary alkyl thioethers are efficiently prepared under mild reaction conditions. The mechanistic pathways involving radical-mediated tandem C–C bond cleavage and C–S bond formation are proposed.

Graphical abstract: Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

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Article information


Submitted
01 Mar 2016
Accepted
29 May 2016
First published
01 Jun 2016

Chem. Commun., 2016,52, 8160-8163
Article type
Communication

Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

R. Ren, Z. Wu and C. Zhu, Chem. Commun., 2016, 52, 8160
DOI: 10.1039/C6CC01843B

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