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Issue 45, 2016
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Synthesis of –C[double bond, length as m-dash]N– linked covalent organic frameworks via the direct condensation of acetals and amines

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Abstract

We demonstrate herein a facile approach for constructing –C[double bond, length as m-dash]N– linked COFs from acetals. Three new COFs (imine-linked LZU-20, hydrazone-linked LZU-21, and azine-linked LZU-22) were synthesized by the direct condensation of dimethyl acetals and amines. All the synthesized COFs are highly crystalline and exhibit good thermal stability.

Graphical abstract: Synthesis of –C [[double bond, length as m-dash]] N– linked covalent organic frameworks via the direct condensation of acetals and amines

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Article information


Submitted
30 Jan 2016
Accepted
12 Apr 2016
First published
19 Apr 2016

Chem. Commun., 2016,52, 7217-7220
Article type
Communication

Synthesis of –C[double bond, length as m-dash]N– linked covalent organic frameworks via the direct condensation of acetals and amines

Z. Li, S. Ding, H. Xue, W. Cao and W. Wang, Chem. Commun., 2016, 52, 7217
DOI: 10.1039/C6CC00947F

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