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Issue 25, 2016
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Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

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Abstract

To employ the full potential of electrochemical (ec) synthesis to grow metal–organic frameworks (MOFs) in more complex organizations at the mesoscale, it is vital to understand the underlying crystallization reaction pathway. For the MOF most typically grown electrochemically, CuBTC, we systematically investigated the role of oxygen species in the synthesis.

Graphical abstract: Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

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Article information


Submitted
19 Jan 2016
Accepted
26 Feb 2016
First published
01 Mar 2016

This article is Open Access

Chem. Commun., 2016,52, 4722-4725
Article type
Communication
Author version available

Unraveling a two-step oxidation mechanism in electrochemical Cu-MOF synthesis

P. Schäfer, M. A. van der Veen and K. F. Domke, Chem. Commun., 2016, 52, 4722
DOI: 10.1039/C6CC00534A

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