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Issue 58, 2016
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Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

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Abstract

The first structure elucidation of a lamellar gold thiolate coordination polymer is described. [Au(p-SPhCO2Me)]n is obtained from the simultaneous esterification of mercaptobenzoic acid and reduction of the Au(III) precursor. Despite the presence of aurophilic interactions, the intense phosphorescence (QY ∼ 70%) originates from intra-ligand and metal-to-ligand transitions.

Graphical abstract: Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

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Supplementary files

Article information


Submitted
21 Dec 2015
Accepted
08 Feb 2016
First published
08 Feb 2016

Chem. Commun., 2016,52, 9063-9066
Article type
Communication

Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

C. Lavenn, N. Guillou, M. Monge, D. Podbevšek, G. Ledoux, A. Fateeva and A. Demessence, Chem. Commun., 2016, 52, 9063
DOI: 10.1039/C5CC10448C

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