Jump to main content
Jump to site search

Issue 15, 2016
Previous Article Next Article

Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines

Author affiliations

Abstract

Iron complex-catalyzed regioselective single hydrophosphination of terminal arylalkynes with secondary phosphines was achieved. Unsymmetric 1,2-bis(phosphino)ethanes with different phosphino groups were obtained by using our catalytic systems. The structures of the obtained vinylphosphine, unsymmetric 1,2-bis(phosphino)ethane, and iron catalyst precursors were confirmed by single crystal X-ray diffraction studies.

Graphical abstract: Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Dec 2015, accepted on 14 Jan 2016 and first published on 25 Jan 2016


Article type: Communication
DOI: 10.1039/C5CC10185A
Chem. Commun., 2016,52, 3163-3166

  •   Request permissions

    Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines

    M. Itazaki, S. Katsube, M. Kamitani and H. Nakazawa, Chem. Commun., 2016, 52, 3163
    DOI: 10.1039/C5CC10185A

Search articles by author

Spotlight

Advertisements