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Issue 26, 2016
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Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

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Abstract

The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.

Graphical abstract: Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

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Article information


Submitted
04 Dec 2015
Accepted
04 Mar 2016
First published
04 Mar 2016

This article is Open Access

Chem. Commun., 2016,52, 4836-4839
Article type
Communication
Author version available

Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

N. Bergemann, C. Pistidda, C. Milanese, T. Emmler, F. Karimi, A.-L. Chaudhary, M. R. Chierotti, T. Klassen and M. Dornheim, Chem. Commun., 2016, 52, 4836
DOI: 10.1039/C5CC09991A

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