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Issue 7, 2016
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The synthesis of sterically hindered amines by a direct reductive amination of ketones

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Abstract

An atom-economical methodology for the synthesis of sterically hindered tertiary amines was developed, which is based on complementary Rh- and Ru-catalyzed direct reductive amination of ketones with primary and secondary amines using carbon monoxide as a deoxygenating agent.

Graphical abstract: The synthesis of sterically hindered amines by a direct reductive amination of ketones

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Article information


Submitted
20 Oct 2015
Accepted
04 Nov 2015
First published
06 Nov 2015

Chem. Commun., 2016,52, 1397-1400
Article type
Communication
Author version available

The synthesis of sterically hindered amines by a direct reductive amination of ketones

N. Z. Yagafarov, P. N. Kolesnikov, D. L. Usanov, V. V. Novikov, Y. V. Nelyubina and D. Chusov, Chem. Commun., 2016, 52, 1397
DOI: 10.1039/C5CC08577B

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