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Issue 21, 2016
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Solid-state polymerisation via [2+2] cycloaddition reaction involving coordination polymers

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Abstract

Highly crystalline metal ions containing organic polymers are potentially useful to manipulate the magnetic and optical properties to make advanced multifunctional materials. However, it is challenging to synthesise monocrystalline metal complexes of organic polymers and single-phase hybrid materials made up of both coordination and organic polymers by traditional solution crystallisation. This requires an entirely different approach in the solid-state by thermal or photo polymerisation of the ligands. Among the photochemical methods available, [2+2] cycloaddition reaction has been recently employed to generate cyclobutane based coordination polymers from the metal complexes. Cyclobutane polymers have also been integrated into coordination polymers in this way. Recent advancements in the construction of polymeric chains of cyclobutane rings through photo-dimerisation reaction in the monocrystalline solids containing metal complexes, coordination polymers and metal–organic framework structures are discussed here.

Graphical abstract: Solid-state polymerisation via [2+2] cycloaddition reaction involving coordination polymers

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Article information


Submitted
08 Oct 2015
Accepted
10 Dec 2015
First published
21 Dec 2015

Chem. Commun., 2016,52, 3989-4001
Article type
Feature Article

Solid-state polymerisation via [2+2] cycloaddition reaction involving coordination polymers

R. Medishetty, I. Park, S. S. Lee and J. J. Vittal, Chem. Commun., 2016, 52, 3989
DOI: 10.1039/C5CC08374E

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