Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

Olivier Jeannin; Enric Canadell; Pascale Auban-Senzier; Marc Fourmigué

doi:10.1039/C5CC08176A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me₂I₂TTF]₂Br†

Olivier Jeannin,^a Enric Canadell,^b Pascale Auban-Senzier^c and Marc Fourmigué*^a

Author affiliations

* Corresponding authors

^a Institut des Sciences Chimiques de Rennes, Université Rennes 1, UMR CNRS 6226, Campus de Beaulieu, 35042 Rennes, France
E-mail: marc.fourmigue@univ-rennes1.fr

^b Institut de Ciència de Materials de Barcelona (CSIC), Campus de la UAB, E-08193 Bellaterra, Spain

^c Laboratoire de Physique des Solides, Université Paris-Sud, UMR CNRS 8502, Bât. 510, 91405 Orsay, France

Abstract

The Z and E isomers of the iodinated TTF derivative (Z,E)-Me₂I₂-TTF co-crystallize in a mixed-valence salt with Br⁻ anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5CC08176A
Article type: Communication
Submitted: 30 Sep 2015
Accepted: 20 Oct 2015
First published: 29 Oct 2015

Download Citation

Chem. Commun., 2016,52, 308-311

Author version available

Download author version (PDF)

Permissions

Request permissions

Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me₂I₂TTF]₂Br

O. Jeannin, E. Canadell, P. Auban-Senzier and M. Fourmigué, Chem. Commun., 2016, 52, 308 DOI: 10.1039/C5CC08176A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications