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Issue 2, 2016
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Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

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Abstract

The Z and E isomers of the iodinated TTF derivative (Z,E)-Me2I2-TTF co-crystallize in a mixed-valence salt with Br anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding.

Graphical abstract: Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

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Publication details

The article was received on 30 Sep 2015, accepted on 20 Oct 2015 and first published on 29 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC08176A
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Chem. Commun., 2016,52, 308-311

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    Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

    O. Jeannin, E. Canadell, P. Auban-Senzier and M. Fourmigué, Chem. Commun., 2016, 52, 308
    DOI: 10.1039/C5CC08176A

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