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Issue 6, 2016
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A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors

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Abstract

A [3Fe–3(μ-S)]3+ cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.

Graphical abstract: A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors

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Article information


Submitted
17 Sep 2015
Accepted
17 Nov 2015
First published
25 Nov 2015

Chem. Commun., 2016,52, 1174-1177
Article type
Communication
Author version available

A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors

Y. Lee, I. Jeon, K. A. Abboud, R. García-Serres, J. Shearer and L. J. Murray, Chem. Commun., 2016, 52, 1174
DOI: 10.1039/C5CC07813J

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