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Issue 3, 2016
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Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water

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Abstract

An amphiphilic polymeric micelle is utilized as a microreactor to load a hydrophobic [FeFe]-hydrogenase mimic in water. The local concentration enhancement and strong interaction between the mimic and the photosensitizer as well as the water-mediated fast proton migration caused by the microreactor improve photocatalytic hydrogen production remarkably in water.

Graphical abstract: Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water

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Article information


Submitted
09 Sep 2015
Accepted
25 Sep 2015
First published
25 Sep 2015

Chem. Commun., 2016,52, 457-460
Article type
Communication

Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water

F. Wang, M. Wen, K. Feng, W. Liang, X. Li, B. Chen, C. Tung and L. Wu, Chem. Commun., 2016, 52, 457
DOI: 10.1039/C5CC07499A

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