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Issue 11, 2016
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A biphenyl containing two electron-donating and two electron-accepting moieties: a rigid and small donor–acceptor–donor ladder system

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Abstract

Ladder π-conjugated materials and also push–pull systems belong to important classes of compounds for the development of organic electronic devices. In this communication, a novel π-conjugated material that unifies the properties of both of these classes is presented. The material comprises a rigid biphenyl framework, which bears two bridging electron-accepting phosphine oxide moieties as well as two electron-donating amino groups. The structure and photophysical properties of this compound are discussed and compared with those of a related system lacking the second P-moiety.

Graphical abstract: A biphenyl containing two electron-donating and two electron-accepting moieties: a rigid and small donor–acceptor–donor ladder system

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Article information


Submitted
13 Apr 2015
Accepted
17 Dec 2015
First published
17 Dec 2015

Chem. Commun., 2016,52, 2374-2377
Article type
Communication
Author version available

A biphenyl containing two electron-donating and two electron-accepting moieties: a rigid and small donor–acceptor–donor ladder system

T. W. Greulich, N. Suzuki, C. G. Daniliuc, A. Fukazawa, E. Yamaguchi, A. Studer and S. Yamaguchi, Chem. Commun., 2016, 52, 2374
DOI: 10.1039/C5CC03063C

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