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Issue 18, 2015
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Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties

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Abstract

A Ca-bridged siloxene (Ca-siloxene) resulting from the deintercalation of Ca from CaSi2 was synthesized via a solid state reaction with ethanol wash using TaCl5. The presence of fragmented, two-dimensional siloxene planes with Ca bridging was confirmed. The Ca-siloxene exhibited tunable optical properties, as well as stable Li storage performance by Ca bridging.

Graphical abstract: Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties

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Publication details

The article was received on 15 Jan 2015, accepted on 24 Mar 2015 and first published on 07 Apr 2015


Article type: Communication
DOI: 10.1039/C5TA00321K
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J. Mater. Chem. A, 2015,3, 9411-9414

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    Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties

    H. Imagawa, N. Takahashi, T. Nonaka, Y. Kato, K. Nishikawa and H. Itahara, J. Mater. Chem. A, 2015, 3, 9411
    DOI: 10.1039/C5TA00321K

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