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Issue 129, 2015
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Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

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Abstract

IR laser ablation was used for the systematic matrix-isolation investigation of reaction products of alkali metal fluorides and fluorine. New insights about periodic trends in the reaction behaviour of alkali metals and the formation as well as the photochemistry of alkali metal trifluorides are presented. New bands were found for the antisymmetric stretches of CsF3 and [F3] in solid krypton and nitrogen, and for the combination bands (νas + νs) of CsF3 and [F3] in solid krypton and argon.

Graphical abstract: Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

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Publication details

The article was received on 16 Nov 2015, accepted on 29 Nov 2015 and first published on 01 Dec 2015


Article type: Paper
DOI: 10.1039/C5RA24227D
RSC Adv., 2015,5, 106568-106573

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    Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

    F. A. Redeker, H. Beckers and S. Riedel, RSC Adv., 2015, 5, 106568
    DOI: 10.1039/C5RA24227D

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