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Issue 129, 2015
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Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

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Abstract

IR laser ablation was used for the systematic matrix-isolation investigation of reaction products of alkali metal fluorides and fluorine. New insights about periodic trends in the reaction behaviour of alkali metals and the formation as well as the photochemistry of alkali metal trifluorides are presented. New bands were found for the antisymmetric stretches of CsF3 and [F3] in solid krypton and nitrogen, and for the combination bands (νas + νs) of CsF3 and [F3] in solid krypton and argon.

Graphical abstract: Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

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Article information


Submitted
16 Nov 2015
Accepted
29 Nov 2015
First published
01 Dec 2015

RSC Adv., 2015,5, 106568-106573
Article type
Paper

Investigation of alkali metal polyfluorides by matrix-isolation spectroscopy

F. A. Redeker, H. Beckers and S. Riedel, RSC Adv., 2015, 5, 106568
DOI: 10.1039/C5RA24227D

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