Issue 130, 2015

Dip- and spin-assisted stereocomplexation-driven LbL self-assembly involving homochiral PVA-g-OLLA and PVA-g-ODLA copolymers

Abstract

Layer by Layer (LbL) thin films stemming from the formation of stereocomplex between oligolactate of opposite chirality (OLLA and ODLA) covalently anchored onto poly(vinyl alcohol) (PVA) chains is described herein for the first time. The feasibility to construct films by sequential adsorption of PVA-g-ODLA and PVA-g-OLLA graft copolymers is undertaken through the exploitation of two different film deposition techniques, namely dip- and spin-assisted processes. For both deposition methods, infrared spectroscopy in ATR mode reveals a progressive accumulation of matter on the flat substrate during the successive cycle depositions and proves that co-crystallisation involving the two homochiral copolymers is the main driving force for the step by step film build up. Also, the effect of the deposition technique is assessed on the film features in terms of (i) growth mechanism, (ii) internal organization and (iii) surface topology. The strong centrifugal forces associated with fast solvent elimination acting during spinning lead to thinner film with more uniform and homogeneous surface morphology in a much shorter time, than the ones resulting from the dip-assisted process. Such LbL nanometric films, induced by OLLA/ODLA interfacial stereocomplexation, open promising perspectives in the field of biodegradable self-assembled films.

Graphical abstract: Dip- and spin-assisted stereocomplexation-driven LbL self-assembly involving homochiral PVA-g-OLLA and PVA-g-ODLA copolymers

Supplementary files

Article information

Article type
Paper
Submitted
28 Oct 2015
Accepted
01 Dec 2015
First published
03 Dec 2015

RSC Adv., 2015,5, 107370-107377

Author version available

Dip- and spin-assisted stereocomplexation-driven LbL self-assembly involving homochiral PVA-g-OLLA and PVA-g-ODLA copolymers

M. Bahloul, S. Pruvost, E. Fleury, D. Portinha and A. Charlot, RSC Adv., 2015, 5, 107370 DOI: 10.1039/C5RA22635J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements