Jump to main content
Jump to site search

Issue 123, 2015
Previous Article Next Article

Tungsten diselenide (WSe2) as a high capacity, low overpotential conversion electrode for sodium ion batteries

Author affiliations

Abstract

Tungsten diselenide (WSe2) is demonstrated as an efficient electrode for sodium ion batteries for the first time. A high reversible capacity above 200 mA h g−1 is observed at 20 mA g−1 rate, with over 250 mA h g−1 capacity measured in the first sodium extraction. Assessment of electrolyte and binder materials on performance was examined and an EC/DEC electrolyte with CMC binder emerges to yield the highest capacity and cycling retention. Comparison between WS2 and WSe2 distinguishes WSe2 to exhibit superior performance due to more efficient energetics bearing a small overpotential <0.30 V. Ex situ analysis and imaging after cycling confirms a sodium-mediated conversion reaction that yields isolated domains of W metal or NaxSe and reformation of WSe2 upon sodium extraction, enabling insight into the chemical storage pathway. This work highlights the promise of WSe2 compared to other conversion-based transition metal dichalcogenides as a practical material for sodium ion batteries.

Graphical abstract: Tungsten diselenide (WSe2) as a high capacity, low overpotential conversion electrode for sodium ion batteries

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Sep 2015, accepted on 12 Nov 2015 and first published on 16 Nov 2015


Article type: Paper
DOI: 10.1039/C5RA19717A
RSC Adv., 2015,5, 101262-101267

  •   Request permissions

    Tungsten diselenide (WSe2) as a high capacity, low overpotential conversion electrode for sodium ion batteries

    K. Share, J. Lewis, L. Oakes, R. E. Carter, A. P. Cohn and C. L. Pint, RSC Adv., 2015, 5, 101262
    DOI: 10.1039/C5RA19717A

Search articles by author

Spotlight

Advertisements