Issue 123, 2015
From the journal:

RSC Advances

Regioisomerized atom transfer radical addition (ATRA) of olefins with dichlorofluorocarbons†

Bo Zhao,a   Ju-You Lu,a   Yang Li,a   Dong-Huai Tu,a   Zhao-Tie Liu,*b   Zhong-Wen Liub  and  Jian Lu*a  

* Corresponding authors

a Department of Catalysis, Xi'an Modern Chemistry Research Institute, Xi'an, China
E-mail: lujian204@263.net
Tel: +86 29 88291213

b Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, China
E-mail: ztliu@snnu.edu.cn
Tel: +86 29 81530802

Abstract

The Cu(I) catalysed atom transfer radical addition of dichlorofluorocarbons to olefins via C–Cl bond homolysis is successfully carried out. Isomerization of vic into gem-dichlorofluorocarbons is observed by using CuCl as a catalyst and TPMA as a ligand, indicating a radical addition mechanism of this reaction procedure.

Graphical abstract: Regioisomerized atom transfer radical addition (ATRA) of olefins with dichlorofluorocarbons

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Article information

DOI
https://doi.org/10.1039/C5RA19244G
Article type
Communication
Submitted
18 Sep 2015
Accepted
16 Nov 2015
First published
18 Nov 2015

RSC Adv., 2015,5, 101412-101415

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Regioisomerized atom transfer radical addition (ATRA) of olefins with dichlorofluorocarbons

B. Zhao, J. Lu, Y. Li, D. Tu, Z. Liu, Z. Liu and J. Lu, RSC Adv., 2015, 5, 101412 DOI: 10.1039/C5RA19244G

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