Issue 93, 2015
From the journal:

RSC Advances

High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group†

Xiao-Jie Han,ab   Hua-Feng Fei,ab   Bo-Zheng Liu,ab   Yong-Xia Tan,a   Xue-Zhong Zhang,a   Ze-Min Xiea  and  Zhi-Jie Zhang*a  

* Corresponding authors

a Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, 100190 Beijing, PR China
E-mail: zhangzj@iccas.ac.cn

b College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing 100049, China

Abstract

An efficient method for the synthesis of organosilicon compounds containing m-carboranylmethyl was developed, which afforded the products in good to excellent yields (up to 88%) compared to the literature methods affording a 38% yield. Moreover, the generated intermediate 5 containing a Si–Br bond could be functionalized conveniently.

Graphical abstract: High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group

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Article information

DOI
https://doi.org/10.1039/C5RA13344K
Article type
Communication
Submitted
08 Jul 2015
Accepted
04 Sep 2015
First published
04 Sep 2015

RSC Adv., 2015,5, 76079-76082

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High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group

X. Han, H. Fei, B. Liu, Y. Tan, X. Zhang, Z. Xie and Z. Zhang, RSC Adv., 2015, 5, 76079 DOI: 10.1039/C5RA13344K

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