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Issue 70, 2015
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Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

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Abstract

The development of Ru-catalyzed asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides is described. The reaction proceeds through dynamic kinetic resolution to afford anti β-hydroxy α-amino esters with good diastereomeric ratios and high enantioselectivities.

Graphical abstract: Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

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Publication details

The article was received on 01 Jun 2015, accepted on 23 Jun 2015 and first published on 23 Jun 2015


Article type: Communication
DOI: 10.1039/C5RA10385A
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RSC Adv., 2015,5, 56815-56819

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    Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

    P. Echeverria, J. Cornil, C. Férard, A. Guérinot, J. Cossy, P. Phansavath and V. Ratovelomanana-Vidal, RSC Adv., 2015, 5, 56815
    DOI: 10.1039/C5RA10385A

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