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Issue 70, 2015
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Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

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Abstract

The development of Ru-catalyzed asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides is described. The reaction proceeds through dynamic kinetic resolution to afford anti β-hydroxy α-amino esters with good diastereomeric ratios and high enantioselectivities.

Graphical abstract: Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

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Supplementary files

Article information


Submitted
01 Jun 2015
Accepted
23 Jun 2015
First published
23 Jun 2015

RSC Adv., 2015,5, 56815-56819
Article type
Communication
Author version available

Asymmetric transfer hydrogenation of α-amino β-keto ester hydrochlorides through dynamic kinetic resolution

P. Echeverria, J. Cornil, C. Férard, A. Guérinot, J. Cossy, P. Phansavath and V. Ratovelomanana-Vidal, RSC Adv., 2015, 5, 56815
DOI: 10.1039/C5RA10385A

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