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Issue 65, 2015
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Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

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Abstract

Phenyl esters were obtained in moderate to high yields by reaction of aliphatic and aromatic carboxylic acids with one equivalent of diphenyl carbonate in the presence of catalytic amounts of tertiary amine bases, such as DBU, TBD and DMAP under neat conditions at elevated temperatures (>100 °C).

Graphical abstract: Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

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Supplementary files

Article information


Submitted
29 May 2015
Accepted
11 Jun 2015
First published
11 Jun 2015

RSC Adv., 2015,5, 53155-53160
Article type
Communication

Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

O. Kreye and M. A. R. Meier, RSC Adv., 2015, 5, 53155
DOI: 10.1039/C5RA10206E

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