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Issue 55, 2015
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Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

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Abstract

The unique properties of pentafluorophenyl vinyl sulfonate allow for a hitherto unmet feat to be realised; efficient and high yielding, metal-free, radical-based alkene hydroacylation employing aldehyde as limiting reagent. The optimised conditions are shown to work in good yields across a series of aldehydes, thus demonstrating the wide applicability of the developed protocol.

Graphical abstract: Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

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Supplementary files

Article information


Submitted
06 May 2015
Accepted
12 May 2015
First published
12 May 2015

RSC Adv., 2015,5, 44423-44426
Article type
Communication

Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

V. Chudasama, RSC Adv., 2015, 5, 44423
DOI: 10.1039/C5RA08353B

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