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Issue 42, 2015
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Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

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Abstract

An oxidative cross-coupling between directing substrates and benzyl bromides via the combined effect of oxidants TBHP and NMO, catalysed by Pd(II) has been investigated. Benzyl bromides served as efficient aroyl surrogates in this substrate directed C–H functionalisation. The in situ generated benzaldehyde originating from benzyl bromide is the active aroylating source.

Graphical abstract: Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

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Article information


Submitted
04 Mar 2015
Accepted
31 Mar 2015
First published
31 Mar 2015

RSC Adv., 2015,5, 33334-33338
Article type
Communication
Author version available

Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

A. Behera, W. Ali, S. Guin, N. Khatun, P. R. Mohanta and B. K. Patel, RSC Adv., 2015, 5, 33334
DOI: 10.1039/C5RA03836G

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