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Issue 34, 2015
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Combining superior surface enhanced Raman scattering and photothermal conversion on one platform: a strategy of ill-defined gold nanoparticles

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Abstract

We report a facile one-pot strategy of “ill-defined gold nanoparticles (ID-GNPs)” to prepare dual functional gold nanoparticles. The ID-GNPs were prepared in a simple way by tuning the morphology of the regular GNPs with a tiny amount of cetyltrimethyl ammonium bromide (CTAB). The prepared ID-GNPs comprise both quasi-spherical and elongated gold nanoparticles, which allow the presence of coarse surfaces and high density of hot spots. The substrates fabricated with ID-GNPs show dramatic Raman enhancement for p-aminothiophenol (PATP). PATP can be detected even at a concentration of 10−12 mol L−1. Meanwhile, these ID-GNPs can efficiently convert absorbed photons into heat when irradiated with 808 nm laser. The temperature of the ID-GNPs dispersion can be enhanced 26.0 °C within 10 minutes, which is capable of inducing the phase transition of a temperature-sensitive supramolecular system. Our study suggests that with the strategy of ‘ill-defined gold nanoparticles’, these two different functionalities can be achieved on one platform.

Graphical abstract: Combining superior surface enhanced Raman scattering and photothermal conversion on one platform: a strategy of ill-defined gold nanoparticles

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Article information


Submitted
05 Feb 2015
Accepted
11 Mar 2015
First published
11 Mar 2015

RSC Adv., 2015,5, 27120-27125
Article type
Paper

Combining superior surface enhanced Raman scattering and photothermal conversion on one platform: a strategy of ill-defined gold nanoparticles

S. Liu, X. Ling, C. Zhou, J. Zhang, J. Huang and Y. Yan, RSC Adv., 2015, 5, 27120
DOI: 10.1039/C5RA02267C

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