This communication reports UV-vis, fluorescence and quantum chemical investigations on the supramolecular interactions of a porphyrazine derivative, namely, 2,7,12,17-tetra-tert-butyl-5,10,15,20-tetraaza-21H,23H-porphine (1) with C60 and C70 in toluene and dichlorobenzene. A synergistic combination of rigidity in the host molecule and a shape-selective binding motif give rise to the strongest binding of C60 with porphyrazine.
A. Ray, H. Pal and S. Bhattacharya, RSC Adv., 2015, 5, 28497 DOI: 10.1039/C5RA02003D
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