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Issue 25, 2015
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Different mechanisms and electrocatalytic activities of Ce ion or CeO2 modified Ti/Sb–SnO2 electrodes fabricated by one-step pulse electro-codeposition

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Abstract

Sb-doped SnO2 electrode was fabricated by the one-step pulse electro-codeposition method, and was modified through either cerium dioxide nanoparticle (nano-CeO2) or cerium ion doping. The results showed that the effects of nano-CeO2 doping and cerium ion doping are quite different. Nano-CeO2 doping shrinks the unit cell volume, improves the degree of crystallinity and refines crystalline grains, while cerium ion doping expands the volume and deteriorates the crystallinity. Nano-CeO2 doping mitigates the surface antimony enrichment and promotes the complete oxidation of antimony so that the majority of antimony oxidation states exist as the Sb5+ state, but cerium ion doping aggravates the enrichment and increases the Sb3+ content. Electrochemical phenol degradation showed that the Ti/Sb–SnO2–CeO2 electrode has a higher degradation efficiency and its kinetic rate constant is 1.46 times as much as that of Ti/Ce–Sb–SnO2. Besides, due to the compact active layer of Ti/Sb–SnO2–CeO2 protecting the titanium substrate from passivation, the accelerated service lifetime of Ti/Sb–SnO2–CeO2 is prolonged, which is 1.28 times as long as that of Ti/Ce–Sb–SnO2.

Graphical abstract: Different mechanisms and electrocatalytic activities of Ce ion or CeO2 modified Ti/Sb–SnO2 electrodes fabricated by one-step pulse electro-codeposition

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Supplementary files

Article information


Submitted
30 Jan 2015
Accepted
05 Feb 2015
First published
09 Feb 2015

RSC Adv., 2015,5, 19601-19612
Article type
Paper
Author version available

Different mechanisms and electrocatalytic activities of Ce ion or CeO2 modified Ti/Sb–SnO2 electrodes fabricated by one-step pulse electro-codeposition

T. Duan, Y. Chen, Q. Wen and Y. Duan, RSC Adv., 2015, 5, 19601
DOI: 10.1039/C5RA01876E

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