Issue 23, 2015
From the journal:

RSC Advances

Guest-induced single-crystal-to-single-crystal transformations of a new 4-connected 3D cadmium(ii) metal–organic framework†

Shi-Hui Li,a   Min-Le Han,a   Guang-Zhen Liu,a   Lu-Fang Ma*a  and  Li-Ya Wang*ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P. R. China
E-mail: mazhuxp@126.com
Fax: +86-379-65511205
Tel: +86-379-65526089

b College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, P. R. China
E-mail: wlya@lynu.edu.cn

Abstract

The hydrothermal reaction of a Cd(II) salt with 4-(pyridin-4-yl)-isophthalic acid (H2pic) yields a new uninodal 4-connected 3D metal–organic framework [Cd(pic)(H2O)]·H2O (1) with the Schläfli symbol of (4·65). 1 and [Cd(pic)] (1a) could undergo single-crystal-to-single-crystal transformation (SC–SC) via reversible dehydration and rehydration.

Graphical abstract: Guest-induced single-crystal-to-single-crystal transformations of a new 4-connected 3D cadmium(ii) metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C5RA00621J
Article type
Paper
Submitted
12 Jan 2015
Accepted
05 Feb 2015
First published
05 Feb 2015

RSC Adv., 2015,5, 17588-17591

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Guest-induced single-crystal-to-single-crystal transformations of a new 4-connected 3D cadmium(II) metal–organic framework

S. Li, M. Han, G. Liu, L. Ma and L. Wang, RSC Adv., 2015, 5, 17588 DOI: 10.1039/C5RA00621J

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