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Issue 14, 2015
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Photomodulable phosphines incorporating diarylethene moieties

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Abstract

Incorporation of the dithienylethene moiety as a substituent provides new ‘switchable’ phosphine ligands whose electronic properties are reversibly modulated by light. The presence of electron-withdrawing substituents in the photochromic unit increases the σ-donation gap between the photo-modulated open and closed phosphine isomers.

Graphical abstract: Photomodulable phosphines incorporating diarylethene moieties

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Publication details

The article was received on 10 Dec 2014, accepted on 07 Jan 2015 and first published on 07 Jan 2015


Article type: Communication
DOI: 10.1039/C4RA16127K
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Citation: RSC Adv., 2015,5, 10795-10798
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    Photomodulable phosphines incorporating diarylethene moieties

    G. Bianchini, G. Strukul, D. F. Wass and A. Scarso, RSC Adv., 2015, 5, 10795
    DOI: 10.1039/C4RA16127K

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