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Issue 1, 2015
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Brønsted acid-catalyzed hydroarylation of activated olefins

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Abstract

A mild, regiospecific Brønsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel–Crafts-type alkylation reaction of electron-rich arenes.

Graphical abstract: Brønsted acid-catalyzed hydroarylation of activated olefins

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Publication details

The article was received on 02 Nov 2014, accepted on 17 Nov 2014 and first published on 19 Nov 2014


Article type: Communication
DOI: 10.1039/C4RA13647K
RSC Adv., 2015,5, 493-496
  • Open access: Creative Commons BY license
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    Brønsted acid-catalyzed hydroarylation of activated olefins

    I. Fleischer and J. Pospech, RSC Adv., 2015, 5, 493
    DOI: 10.1039/C4RA13647K

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