Issue 10, 2015
From the journal:

Organic Chemistry Frontiers

Pincer CNC bis-N-heterocyclic carbenes: robust ligands for palladium-catalysed Suzuki–Miyaura arylation of bromoanthracene and related substrates†

V. M. Zende,a   C. Schulzkeb  and  A. R. Kapdi*a  

* Corresponding authors

a Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai-400019, India
E-mail: ar.kapdi@ictmumbai.edu.in

b Institute fur Biochemie, Ernst-Moritz-Arndt Universität Greifswald, Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany

Abstract

Novel pincer-type N-heterocyclic carbene ligands have been synthesised and characterised by FAB-MS and single crystal X-ray analysis. The ligands have proved to be highly active towards palladium-catalysed Suzuki–Miyaura cross-coupling of bromoanthracene and related substrates allowing the efficient and easy access of molecules for possible OLED applications.

Graphical abstract: Pincer CNC bis-N-heterocyclic carbenes: robust ligands for palladium-catalysed Suzuki–Miyaura arylation of bromoanthracene and related substrates

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Article information

DOI
https://doi.org/10.1039/C5QO00236B
Article type
Research Article
Submitted
26 Jul 2015
Accepted
24 Aug 2015
First published
02 Sep 2015

Org. Chem. Front., 2015,2, 1397-1410

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Pincer CNC bis-N-heterocyclic carbenes: robust ligands for palladium-catalysed Suzuki–Miyaura arylation of bromoanthracene and related substrates

V. M. Zende, C. Schulzke and A. R. Kapdi, Org. Chem. Front., 2015, 2, 1397 DOI: 10.1039/C5QO00236B

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